
This scanning electron micrograph shows carbon-coated silicon nanoparticles on the surface of the composite granules used to form the new anode. Source: Georgia Tech. Click to enlarge.
Researchers have developed a new high-performance anode structure for lithium-ion batteries based on silicon-carbon nanocomposite materials. Produced via large-scale hierarchical bottom-up assembly, the material contains rigid and robust silicon spheres with irregular channels for rapid access of Li ions into the particle bulk.
The large silicon volume changes on lithium ion insertion and extraction—which can cause structural problems leading to rapid capacity loss—are accommodated by the particle’s internal porosity. The researchers have shown reversible capacities more than five times higher than that of the state-of-the-art graphite anodes (1,950 mAh g-1) and stable performance. The synthesis process is simple, low-cost, safe and broadly applicable, they say, providing new avenues for the rational engineering of electrode materials with enhanced conductivity and power.
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Source: cleanenergyguy.com
